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Functional Group Reactions and Online Question Bank

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Posted: 09 Sep, 2007
by: Baba S.

Updated: 14 Oct, 2007
by: Baba S.

Functional Group Reactions

Alkanes

Substitution (of H by halogen)

Practice Problems

Alkenes

Electrophilic Additions

Strong Brønsted Acids

Lewis Acids (non-Proton Electrophiles)

Electrophilic Halogen Reagents

Other Electrophilic Reagents

Radical Additions

Allylic Substitution

Practice Problems

Addition Reactions

Diels-Alder Cycloaddition

Practice Problems

Alkynes

Addition Reactions

Hydration & Tautomerism

Nucleophilile Addition & Reduction

Acidity of Terminal Alkynes (Substitution of H)

Practice Problems

Alkyl Halides

General Reactivity

Substitution(of X)

Elimination (of HX)

Summary of Substiution vs. Elimination

Substitution by Metals

Elimination Reactions of Dihalides

Practice Problems

Alcohols

Reactions of Alcohols

Substitution of the Hydroxyl H

Substitution of the Hydroxyl Group

Elimination of Water

Oxidation of Alcohols

Reactions of Phenols

Acidity of Phenols

Ring Substitution of Phenols

Oxidation to Quinones

Practice Problems

Ethers

Preparation of Ethers

Reactions of Ethers

Peroxide Formation

Epoxide Reactions

Practice Problems

Thiols & Sulfides

Sulfur Analogs of Alcohols & Ethers

Benzene & Derivatives

Electrophilic Substitution

A Substitution Mechanism

Reactions of Substituted Benzenes

Reaction Characteristics

Reactions of Disubstituted Rings

Reactions of Substituent Groups

Nucleophilic Substitution, Elimination & Addition Reactions

Practice Problems

Amines

Nomenclature & Structure

Properties of Amines

Boiling Point & Solubility

Basicity of Nitrogen Compounds

Acidity of Nitrogen Compounds

Important Reagent Bases

Reactions of Amines

Electrophilic Substitution at Nitrogen

Preparation of 1º-Amines

Preparation of 2º & 3º-Amines

Practice Problems

Reactions with Nitrous Acid

Reactions of Aryl Diazonium Intermediates

Elimination Reactions of Amines

Oxidation States of Nitrogen

Practice Problems

Phosphines

Phosphorus Analogs of Amines

Aldehydes & Ketones

Nomenclature of Aldehydes & Ketones

Occurrence of Aldehydes & Ketones

Natural Products

Synthetic Preparation

Properties of Aldehydes & Ketones

Reversible Addition Reactions

Hydration & Hemiacetal Formation

Acetal Formation

Imine Formation

Enamine Formation

Cyanohydrin Formation

Irreversible Addition Reactions

Complex Metal Hydrides

Organometallic Reagents

Carbonyl Group Modification

Wolff-Kishner Reduction

Clemmensen Reduction

Hydrogenolysis of Thioacetals

Reactions at the α-Carbon

Mechanism of Electrophilic α-Substitution

The Aldol Reaction

Ambident Enolate Anions

Alkylation of Enolate Anions

Practice Problems

Carboxylic Acids

Nomenclature of Carboxylic Acids

Natural Products

Related Derivatives

Physical Properties

Preparation of Carboxylic Acids

Reactions of Carboxylic Acids

Substitution of Hydroxyl Hydrogen

Substitution of the Hydroxyl Group

Reduction & Oxidation

Practice Problems

Carboxylic Derivatives

Physical Properties

Reactions of Carboxylic Acid Derivatives

Acyl Group Substitution

Catalytic Reduction

Metal Hydride Reduction

Diborane Reduction

Reaction with Organometallic Reagents

Practice Problems

Reactions at the α Carbon

Acidity of α C–H

The Claisen Condensation

Synthesis Applications

Practice Problems

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